标题：Heterostructured Fe2O3@SnO2 core-shell nanospindles for enhanced Room-temperature HCHO oxidation

作者：Lv, T (Lv, Teng); Peng, C (Peng, Chuang); Zhu, H (Zhu, Hua); Xiao, W (Xiao, Wei)

来源出版物：APPLIED SURFACE SCIENCE卷：457页码:83-92DOI：10.1016/j.apsusc.2018.06.254出版年：NOV 1 2018

摘要：Heterostructures combining structural and compositional merits of individual building blocks are promising in advanced catalysis for environmental remediation. We herein report a facile construction of Fe2O3@SnO2 core-shell nanospindles via assembly of SnO2 shells over Fe2O3 cores. With loading of trace N nanoparticles, the Pt/Fe2O3@SnO2 shows enhanced room-temperature HCHO oxidation activity to the Pt/Fe2O3 and Pt/SnO2. Density Function Theory (DFT) simulations demonstrate the synergetic effects of the Fe2O3 and SnO2 in the Fe2O3@SnO2, with the Fe2O3 cores facilitating adsorption/activation of reactant O-2 and the SnO2 shells promoting desorption of reactant H2O. The present study highlights advantages of heterostructure and provides a rational design strategy for advanced catalysts.

入藏号：WOS:000441872300009

文献类型：Article

语种：English

作者关键词：Heterostructure; Room-temperature HCHO oxidation; Fe2O3; SnO2; Indoor-air purification

扩展关键词：POROUS SNO2 MICROSPHERES; GAS-SENSING PROPERTIES; FORMALDEHYDE OXIDATION; INDOOR FORMALDEHYDE; CATALYTIC-OXIDATION; PHOTOCATALYTIC ACTIVITY; AMBIENT-TEMPERATURE; EFFICIENT REMOVAL; PT/TIO2 CATALYST; GOLD CATALYSTS

通讯作者地址：Xiao, W (reprint author), Wuhan Univ, Sch Resource & Environm Sci, Hubei Int Sci & Technol Cooperat Base Sustainable, Wuhan 430072, Hubei, Peoples R China.

电子邮件地址：gabrielxiao@whu.edu.cn

地址：

[Lv, Teng; Peng, Chuang; Zhu, Hua; Xiao, Wei] Wuhan Univ, Sch Resource & Environm Sci, Hubei Int Sci & Technol Cooperat Base Sustainable, Wuhan 430072, Hubei, Peoples R China.

影响因子：4.439